Product ID:CP-32 CHIL-PERM NF
MSDS Date:06/12/1985
FSC:8030
NIIN:00N009931
MSDS Number: BHFXQ

CHILDERS PRODUCTS CO

2061 HARTEL
BRISTOL, PA 19007

Emergency Phone: 215-943-7600

Info Phone: 215-943-7600

Preparer: ROBERT ANDREWS

Cage: 3K675

CHILDERS PRODUCTS CO INC

BRISTOL, PA 19007-0505 US

Cage: 3K675

ANTIMONY TRIOXIDE (SARA III)

CAS: 1309-64-4

RTECS: CC5650000

Fraction By Weight: 1%

OSHA PEL 0.5 MG/M3 (SB)

ACGIH TLV: 0.5 MG SB/M3; 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TITANIUM DIOXIDE

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 6%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST; 9293

CALCIUM CARBONATE.ACGIH TWA IS FOR TOTAL DUST CONTAINING NO

CAS: 471-34-1

RTECS: FF9335000

Fraction By Weight: 4%

OSHA PEL N/K

ACGIH TLV: 10 MG/CUM TWA (1989)

METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III)

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 62%

OSHA PEL 350 PPM/450 STEL

ACGIH TLV: 350 PPM/450STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:N/K
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:PROLONGED OR REPEATED SKIN CONTACT CAN
CAUSE DERMATITIS THROUGH DEFATTING OF SKIN.EXTREME OVEREXPOSURE BY
INHALATION MAY CAUSE CARDIAC ARRHYTHMIAS (IRREGULAR HEARTBEATS).
Explanation of Carcinogenicity:1,1,1-TRICHLOROETHANE.NO ADEQ DATA TO
DETERM CARCIN IN HUM,INADEQ EVID FOR CARCIN IN ANIMALS (IARC
1987).(SEE SUPP DATA)
Effects of Overexposure:EYES:MAY CAUSE PAIN.MAY CAUSE SLIGHT TRANSIENT
IRRIT W/ SLIGHT TRANSIENT CORNEAL INJURY.VAP MAY IRRITATE
EYES.SKIN:ABSORPTION THRU SKIN IS NOT SERIOUS ROUTE OF EXPOS.MILDLY
IRRIT ON CONT.INGEST:N/K (F P N/ORNL).INH:MAHOR ROUTE OF EXPOS-LOW
SYSTEMIC TOXICITY:ACUTE EXPOS IS IN 1000 PPM RANGE & MAY LEAD TO
NARCOS.(SEE SUP)
Medical Cond Aggravated by Exposure:N/K

First Aid:EYES:FLUSH W/ LG AMTS OF H*2O FOR AT LEAST 15 MIN.GET IMMED
MED ATTN.SKIN:WASH THOROUGHLY W/ SOAP & LG QTY OF WATER & GET MED
ATTN IF IRRIT PERSISTS.INGEST:DO NOT INDUCE VOM.GET IMMED MED
ADVICE &/OR ATTN.INHAL:IF BRTHG DFCLTY,DIZZ OR LT HEAD OCCUR WHEN
WORKING IN AREAS W/ HIGH VAP CONC.VICTIM SHOULD SEEK FRESH AIR.IF
BRTHG DFCLTY CONTINUES,GIVE O*2 UNTIL MED HELP CAN BE OBTAINED.IF
(SEE SUP DATA)

Extinguishing Media:WILL NOT BURN IN THE WET STATE.WATER,FOAM,CARBON
DIOXIDE OR DRY CHEMICAL WHEN DRY.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
.WATER MAY BE HELPFUL IN KEEPING ADJACENT CNTNRS COOL.AVOID
SPREADING BURNING LIQ W/ H*2O USED FOR COOLING.
Unusual Fire/Explosion Hazard:AVOID OPEN FLAMES,WELDING ARCS/OTHER HIGH
TEMP SOURCES WHICH COULD INDUCE THERMAL DECOMP.HAZ DECOMP
PROD:THERMAL DECOMP MAY YIELD CO,CO*2,HCL,PHOSGENE .

Spill Release Procedures:MATERIAL WILL NOT FLOW.VENTILATE.AVOID
BREATHING VAPORS,SCRAPE MATERIAL INTO CONTAINERS.KEEP MATERIAL OUT
OF WATER SUPPLIES.
Neutralizing Agent:N/K

Handling and Storage Precautions:HANDLE WITH REASONABLE CARE.AVOID
BREATHING VAPORS.STORE IN COOL,DRY VENTILATED AREAS.VAPORS ARE
HEAVIER THAN AIR AND WILL COLLECT IN LOW AREAS.
Other Precautions:NO SMOKING IN AREA OF USE.DO NOT USE IN GENERAL
VICINITY OF ARC WELDING.OPEN FLAMES OR HOT SURFACES.HEAT AND/OR UV
RADIATION MAY CAUSE FORMATION OF HCL AND/OR PHOSGENE .

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR
CONCENTRATION BELOW TLV .
Protective Gloves:IMPERMEABLE GLOVES ARE ADVISED.
Eye Protection:CHEM WORK GOGG,FACESHLD OPTIONAL .
Other Protective Equipment:IMPERMEABLE APRONS ARE ADVISED WHEN WORKING
W/ PROD.AVAILABILITY OF EYE WASHES & SAFETY SHOWERS IN WORK AREA IS
RECOM.
Work Hygienic Practices:N/K
Supplemental Safety and Health
EXPLAN OF CARCIN:TITANIUM DIOXIDE:CARCIN IN HUM NOT DETERM,SUFF NEG
EVID FOR CARCIN IN ANIM (GENE-TOX 1987).SIGNS & SYMP:OVEREXP CAN
CAUSE DIZZ,DRUNKENNESS,DROW,UNCON & EVEN DEATH @ EXTREME DOSES.FIRS
T AID PROC:BRTHG STOPS,BEGIN ARTF RESP.GET IMMED MED ATTN.NEVER
GIVE ADRENALINE/SYMPATHOMIMETIC DRUG UNLESS ABSOLUT NEC.

Boiling Pt:B.P. Text:165F.74C
Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Spec Gravity:1.5 (WATER=1)
Evaporation Rate & Reference:2.7 (ETHER=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:THICK PASTE,SHARP SOLVENT ODOR.
Percent Volatiles by Volume:67

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS,STRONG ACIDS & BASES AND SELECTED AMINES.
Stability Condition to Avoid:N/K
Hazardous Decomposition Products:THERMAL DECOMPOSITION IN PRESENCE OF
AIR MAY YIELD CARBON MONOXID AND/OR CARBON DIOXIDE,HCL & PHOSGENE .
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS .INCINERATE ACCORDING TO ALL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.